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Andrey Rogachev

Andrey Rogachev, Ph.D.

Andrey Rogachev, Ph.D.
Assistant Professor of Chemistry






390 Robert A. Pritzker Science Center


Ph.D. Chemistry, Moscow State University


Chemistry at magnetic centers, theoretical point of view; luminescence and bioluminescence; chemistry and physics of curved polyaromatic systems (buckybowls and fullerenes); multi-reference approach to spectroscopic, magnetic and catalytic properties of organic, organometallic and bio-(in)organic systems.


  • *C. Farber, J. Li, E. Hager, R. Chemelewski, J. Mullet, A.Yu.Rogachev, D. Kurouski, “Complementarity of Raman and Infrared Spectroscopy for Structural Characterization of Plant Epicuticular Waxes” //*ACSOmega*,2019, *4*, 3700-3707. [ view online» ]

  • *A.Yu. Rogachev,Z. Zhou, S. Liu, Q.Xu, J. Li, S.N.Spisak, Z. Wei, M.A. Petrukhina, “Placing Metal in the Bowl: Does RimcAlkylation Matter?” // *Organometallics*, 2019, *38*, 552-566. [view online>>]

  • *H. Han, Z. Wei, A.S. Filatov, J.C. Carozza, M. Alkan, A.Yu.Rogachev, A. Shevtsov, A.M. Abakumov, C. Pak, M. Shatruk, Y.-S. Chen,E.V.Dikarev, “Three to Tango Requires Some Substitutional Flexibility: Hetertrimetallic Li-Mn-Co Molecular Precursor” // *Chem. Sci.*, 2019,*10*,524-534. [ view online» ]

  • *J. Li, D. Tadakamalla, A.Yu. Rogachev,“ModulatingStability of Functionalized Cations [R-C60]+ with the Nature of R-Group”// *J.Comput. Chem*., 2018, *39*, 2385-2396. [ view online» ]

  • *S. Liu, A.Yu. Rogachev, “Comprehensive TheoreticalStudy of Interactions between Ag+ and Polycyclic Aromatic Hydrocarbons” //*ChemPhysChem.*, 2018, *19*, 2579-2588. [ view online» ]

  • A.V. Zabula, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina, “Record Alkali Metal Intercalation by Highly-Charged Bowls” // Acc. Chem. Res., 2018, 51, 1541-1549. DOI:10.1021/acs.accounts.8b00141 [ view online » ]

  • H. Han, Z. Wei, M.C. Barry, J.C. Carozza, M. Alkan, A.Yu. Rogachev, A.S. Filatov, A.M. Abakumov, E.V. Dikarev, “Three body problem: genuine heterotrimetallic vs. a statistical mixture of two parent heterobimetallic molecules” // Chem. Sci., 2018, ASAP. DOI:10.1039/C8SC00917 [ view online » ]
    • Selected for Cover Page.
  • J.J. Hrudka, H. Phan, A.Yu. Rogachev, M. Shatruk, “The Power of Three: Incremental Increase in the Field Strength of N-Alkylated 2,2'-Biimidazoles Leads to Spin Crossover in Homoleptic Fe(II) Complexes” // Inorg. Chem., 2018, 57, 5183-5193. [ view online » ]
  • S.N. Spisak, A.V. Zabula, M. Alkan, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina, “Site-Directed Dimerization of Bowl-Shaped Radicals to Form a s-Bonded Charged Dibenzocorannulene Dimer” // Angew. Chem., Int. Ed., 2018, 57, 6171-6175. [ view online » ]
  • Z. Zhou, Q. Xu, A.Yu. Rogachev, S.N. Spisak, Z. Wei, M. Marcaccio, M.A. Petrukhina, “Fusing Planar Group to a p-Bowl: Electronic and Molecular Structure, Aromaticity and Solid State Packing of Naphthocorannulene and its Anions” // Chem. Eur. J., 2018, 24, 2455-3463. [ view online » ]
    • Selected for Cover Page.
  • S.N. Spisak, J. Li, A.Yu. Rogachev, Z. Wei, T. Amaya, T. Hirao, M.A. Petrukhina, “Crown Ether-Assisted Convex Cesium Binding to Sumanenyl Bowl” // Organometallics, 2017, 36, 4961-4967. [ view online » ]
  • S. Shokri, J. Li, M.K. Manna, G. Wiederrecht, D.J. Gosztola, A. Ugrinov, S. Jockusch, A.Yu. Rogachev, A.J.-L. Ayitou “A Naphtho-p-quinodimethane Exhibiting Baird’s (Anti-)Aromaticity, Broken Symmetry and Attractive Photoluminescence” // J. Org. Chem., 2017, 82, 10167-10173. [ view online » ]
  • A.Yu. Rogachev, J. Li, M.A. Petrukhina “Exploring Energetics in Dirhodium Paddle-Wheel Complexes with p-Ligands of Different Topologies” // J. Organomet. Chem., 2017, 849-850, 22-30. ( invited article) [ view online » ]
  • C.M. Lieberman, M.C. Barry, Z. Wei, A.Yu. Rogachev, X. Wang, J.-L. Liu, R. Clérac, Y.-S. Chen, A.S. Filatov, E.V. Dikarev “Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials” // Inorg. Chem., 2017, 56, 9574-9584. [ view online » ]
  • Q. Xu, M.A. Petrukhina, A.Yu. Rogachev, “Stepwise Deprotonation of Sumanene: Electronic Structure, Energetics and Aromaticity Alterations” // Phys. Chem. Chem. Phys., 2017, 19, 21575-21583. [ view online » ]
  • S. N. Spisak, A.Yu. Rogachev, A. V. Zabula, A. S. Filatov, R. Cléracde, and M. A. Petrukhina, "Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts," // Chem. Sci., 2017, 8, 3137-3145. [ view online » ]
  • S. N. Spisak, Z. Wei, A.Yu. Rogachev, T. Amaya, T. Hirao, and M. A. Petrukhina, "Double Concave Cesium Encapsulation by Two Charged Sumanenyl Bowls" // Angew. Chem., Int. Ed., 2017, 56, 2582-2587. [ view online » ]
    • Selected for Cover Page.
  • A.V. Zabula, I. Guzei, R. West, J. Li, A.Yu. Rogachev, “Thermal Oligomerization of N-Heterocyclic Silylene into Zwitter-Ionic Silenes” // Angew. Chem., Int. Ed., 2016, 55, 13465-13469. [ view online » ]
  • S. Spisak, J. Li, A.Yu. Rogachev, Z. Wei, O. Papaianina, K. Amsharov, A. Rybalchenko, A. Goryunkov, M. Petrukhina, “From Corannulene to Indacenopicene: Effect of Carbon Framework Topology on Aromaticity and Reduction Limits” // Organometallics, 2016, 35, 3105-3111. [ view online » ]
    • Selected for Cover Page.
  • J. Li, G. da Silva Ramos, A.Yu. Rogachev, “Stability of Functionalized Corannulene Cations [R-C20H10]+: An Influence of the Nature of R-Group” // J. Comput. Chem., 2016, 37, 2266-2278. [ view online » ]
    • Selected for Cover Page.
  • J. Li, A.Yu. Rogachev, “Aromatic Stabilization of Functionalized Corannulene Cations” // Phys. Chem. Chem. Phys., 2016, 18, 11781-11 (invited article).
  • A.V. Zabula, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, V.M. Grigoryants, M.A. Petrukhina “Supramolecular Trap for a Transient Corannulene Trianion” // Chem. Sci., 2016, 7, 1954-1961. [ view online » ]
  • Y. Chen, X. Sun, J. Li, Y. Zhong, S. Jin, Z. Liu, N. Wu, A.Yu. Rogachev, H.-S. Chong “Synthetic and Mechanistic Investigation on One-Pot Halogenation of b-Amino Alcohols and Nucleophilic Ring Opening of Aziridinium Ions” // Org. Biomolec. Chem., 2016, 14, 920-939.
  • S.N. Spisak, Z. Wei, N.J. O’Neil, A.Yu. Rogachev, T. Amaya, T. Hirao, M.A. Petrukhina “Convex and Concave Encapsulation of Multiple Potassium Ions by Sumanenyl Anions” // J. Am. Chem. Soc., 2015, 137, 9768-9771. [ view online » ]
    • Highlighted in Computational Chemistry Highlights: September Issue, 2015.
    • Highlighted in Computational Organic Chemistry: “Sumanene Anions,” September 2015
  • C. Dubceac, A.S. Filatov, A.V. Zabula, A.Yu. Rogachev, M.A. Petrukhina “Functionalized Corannulene Carbocations: A Structural Overview” // Chem. Eur. J., 2015, 21, 14268-14279. [ view online » ]
    • Selected for Cover page.
  • A.Yu. Rogachev, M.-S. Miao, G. Merino, R. Hoffmann “Molecular CsF5 and CsF2+” // Angew. Chem., Int. Ed., 2015, 54, 8275-8278. [ view online » ]
  • C.M. Lieberman, A.S. Filatov, Z. Wei, A.Yu. Rogachev, A.M. Abakumov, E.V. Dikarev “Mixed-Valent, Heteroleptic Homometallic Diketonates as Templates for the Design of Heterometallic Precursors” // Chem. Sci., 2015, 6, 2835-2845. [ view online » ]
  • A.S. Filatov, S.N. Spisak, A.V. Zabula, J. McNeely, A.Yu. Rogachev, M.P. Petrukhina “Dynamic Transformations of Self-Assembled Sandwich Products Formed by Tetrareduced Corannulene with Mixed Core Alkali Metal Clusters” // Chem. Sci., 2015, 6, 1959-1966. [ view online » ]
  • J. Li, A.Yu. Rogachev “SO2 – Yet Another Two-Faced Ligand” // Phys. Chem. Chem. Phys., 2015, 17, 1987-2000.
  • A.V. Zabula, A.Yu. Rogachev, R. West “Self-Assembly of N-Heterocyclic Derivatives of Divalent Germanium, Tin and Lead” // Chem. Eur. J., 2014, 20, 16652-16656. [ view online » ]
  • N. Sumner, S. Spisak, A. Zabula, A. Filatov, A. Rogachev, M. Petrukhina “Alkali Metal Intercalation in Curved Carbon Networks: X-Ray Structural Study” // Acta. Cryst., Sect. A, 2014, A70, C986.
  • N.S. Sumner, S.N. Spisak, A.S. Filatov, A.Yu. Rogachev, A.V. Zabula, M.A. Petrukhina “Double Concave Binding of Bicorannulenyl Dianion: Cesium vs. Lithium Salts” // Organometallics, 2014, 33, 2874-2878. [ view online » ]
  • A.S. Filatov, A.V. Zabula, S.N. Spisak, A.Yu. Rogachev, M.A. Petrukhina “Clamshell effect of highly charged corannulene decks for maximizing the intercalated content in the mixed metal supramolecular aggregates” // Angew. Chem., Int. Ed., 2014, 53, 140-145. [ view online » ]
    • Highlighted in Nature Chemistry: “Metals in the Middle”, Nature Chem., 2014, 6, 4.

Selected Publications Before Professor Rogachev Joined Illinois Institute of Technology

  • A.Yu. Rogachev, R. Hoffmann. Iodine (I2) as a Janus-Faced Ligand in Organometallics. J. Am. Chem. Soc., 2013, 135, 3262. [ view online » ]
  • A.Yu. Rogachev, X.-D. Wen, R. Hoffmann. Jail-Breaking Benzene Dimers. J. Am. Chem. Soc., 2012, 134, 8062. [ view online » ]
  • A.Yu. Rogachev, A.S. Filatov, A. Zabula, M. A. Petrukhina, Functionalized Corannulene Cations: Detailed Theoretical Survey. Phys. Chem. Chem. Phys., 2012, 14, 3554.
  • A.Yu. Rogachev, P. Burger. Bonding Situation and N–O-Bond Strength in Amine-N-Oxides—A Combined Experimental and Theoretical Study. Phys. Chem. Chem. Phys., 2012, 14, 1985.
  • A.V. Zabula, A.S. Filatov, S.N. Spisak, A.Yu. Rogachev, M.A. Petrukhina. A Main Group Metal Sandwich: Five Lithium Cations Jammed Between Two Corannulene Tetraanion Decks. Science, 2011, 333, 1008. [ view online » ]
  • S.N. Spisak, A.V. Zabula, A.S. Filatov, A.Yu. Rogachev, M.A. Petrukhina. Selective Endo and Exo Binding of Alkali Metals to Corannulene. Angew. Chem., Int. Ed., 2011, 50, 8090. [ view online » ]

Professional Societies 

American Chemical Society
Royal Society of Chemistry
American Association for the Advancement of Science